When you're hosting the year's biggest awards night, it pays to look hot. Elegance is the order of the day (and night) and Anne Hathaway delivered old Hollywood charm in this vintage red taffeta gown by Valentino Haute Couture.
The gown from the designer's Fall 2002 Couture collection had a train and floral appliqué. The train gown from the designer's Fall 2002 Couture collection had floral applique detailing in the back; contrasted by diamonds from Tiffany & Co., it was the perfect blend of classic design and bold color. Hathaway, with hair swept back and away from the face, let her dress play the main attraction. And what better person to pose for the cameras with than Valentino himself!